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$HackaMol::Roles::QmMolRole::VERSION = '0.052'; |
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#ABSTRACT: provides attributes needed for quantum chemistry calculations |
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# this will need updating as needs arise |
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use Moose::Role; |
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with 'HackaMol::Roles::QmAtomRole'; |
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has 'multiplicity', is => 'rw', isa => 'Int', lazy => 1, default => 1; |
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my @tscl = qw( |
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score |
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energy |
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Etot Eelec Enuc |
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qm_dipole_moment ionization_energy gradient_norm |
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Hform |
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U H G S |
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S_t |
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S_r |
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S_v |
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Etot_mp2 |
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Etot_ccsdt |
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Ecds |
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); |
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has "$_" => ( |
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traits => ['Array'], |
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is => 'ro', |
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isa => 'ArrayRef[Num]', |
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default => sub { [] }, |
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handles => { |
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"push_$_" => 'push', |
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"get_$_" => 'get', |
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"all_$_" => 'elements', |
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"clear_$_" => 'clear', |
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"count_$_" => 'count', |
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}, |
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lazy => 1, |
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) foreach @tscl; |
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has "$_" => ( |
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traits => ['Array'], |
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is => 'ro', |
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isa => 'ArrayRef[Math::Vector::Real]', |
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default => sub { [] }, |
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handles => { |
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"push_$_" => 'push', |
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"get_$_" => 'get', |
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"all_$_" => 'elements', |
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"clear_$_" => 'clear', |
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"count_$_" => 'count', |
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}, |
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lazy => 1, |
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) for qw(qm_dipole frequencies eigvec alpha beta); |
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no Moose::Role; |
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1; |
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=pod |
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=head1 NAME |
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HackaMol::Roles::QmMolRole - provides attributes needed for quantum chemistry calculations |
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=head1 VERSION |
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version 0.052 |
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=head1 SYNOPSIS |
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# instance of class that consumes the QmMolRole. |
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$obj->multiplicity(1); |
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my @energies = $mol->all_Etot; |
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=head1 DESCRIPTION |
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QmMolRole provides attributes that will be useful for setting up interfaces to |
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quantum chemistry packages. This role consumes the QmAtomRole so there is some |
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overlap for basis_geom, basis, and ecp. For interfaces, the Molecule should |
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take precedence over the atom; i.e. if a Molecule has a basis of 6-31G*, that |
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should be used for all atoms regardless of the basis set that they may have. |
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All attributes are 'rw' and lazy, so they will not contaminate the namespace |
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unless called upon. QmMolRole has 'basis_atoms' that should be generated from the |
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binned unique atoms in a molecule. basis_atoms are just instances of the |
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HackaMol::Atom class with all the basis sets and effective core potentials loaded, |
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either as simple strings supported by the package or the full descriptions |
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pulled from the EMSL basis set exchange as a single Str. |
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https://bse.pnl.gov/bse/portal |
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A dream is to interface with EMSL library directly. Attributes below are |
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described without much detail; they will contain information mapped from |
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calculations and are not exhaustive. This role will probably evolve as |
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interfaces are added. |
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=head1 ATTRIBUTES |
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=head2 multiplicity |
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isa Int that is lazy and rw |
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=head2 Etot Eelec Enuc |
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each isa ArrayRef[Num] that is lazy with public ARRAY traits: push_$_ get_$_ |
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all_$_ clear_$_ count_$_ |
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=head2 qm_dipole_moment ionization_energy gradient_norm Hform |
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each isa ArrayRef[Num] that is lazy with public ARRAY traits: push_$_ get_$_ |
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all_$_ clear_$_ count_$_ |
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=head2 U H G S S_t S_r S_v |
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each isa ArrayRef[Num] that is lazy with public ARRAY traits: push_$_ get_$_ |
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all_$_ clear_$_ count_$_ |
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=head2 Etot_mp2 Etot_ccsdt Ecds |
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each isa ArrayRef[Num] that is lazy with public ARRAY traits: push_$_ get_$_ |
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all_$_ clear_$_ count_$_ |
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=head2 qm_dipole frequencies eigvec alpha beta |
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each isa ArrayRef[Math::Vector::Real] that is lazy with public ARRAY traits: push_$_ get_$_ |
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all_$_ clear_$_ count_$_ |
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=head1 SEE ALSO |
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=over 4 |
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=item * |
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L<HackaMol::Molecule> |
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=item * |
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L<EMSL | https://bse.pnl.gov/bse/portal> |
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=back |
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=head1 CONSUMES |
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=over 4 |
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=item * L<HackaMol::Roles::QmAtomRole> |
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=back |
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=head1 AUTHOR |
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Demian Riccardi <demianriccardi@gmail.com> |
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154
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=head1 COPYRIGHT AND LICENSE |
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This software is copyright (c) 2017 by Demian Riccardi. |
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This is free software; you can redistribute it and/or modify it under |
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the same terms as the Perl 5 programming language system itself. |
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=cut |